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A rate constant for CH2(3B1) + CH3 |
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| Authors: | MJ Pilling JA Robertson |
| Institution: | Physical Chemistry Laboratory, Oxford, UK |
| Abstract: | Triplet methylene, CH2(3B1), and methyl radicals were produced by flash photolysis of a mixture of ketene and azomethane. A computer fit of the product ratios, using the known rate constants for CH2 + CH2, and CH3 + CH3, requires a rate constant of 5.0 × 10?11 cm3 molecule?1s?1 for the reaction CH2 + CH3 ? C2H4 + H. |
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