Laser driven synthesis of BHCl2 from BCl3 and H2 |
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| Authors: | S.D. Rockwood J.W. Hudson |
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| Affiliation: | Los Alamos Scientific Laboratory, University of California, Los Alamos, New Mexico 87544, USA |
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| Abstract: | Mixtures of BCl3 and H2 have been irradiated by a pulsed CO2 laser yielding BCHl2 and HCl as the only products. Approximately 50% conversion of the reagents was obtained with a quantum efficiency of 122 10.6 μ photons per BCHl2 molecule. The product yield is observed to scale with laser power as (P/P0)1.26. |
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