Single vibronic level photochemistry of NO2 in the 2491 Å system |
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| Authors: | William M. Uselman Edward K.C. Lee |
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| Affiliation: | Department of Chemistry, University of California, Irvine, California 92664, USA |
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| Abstract: | A photochemical decomposition study of NO2(B?2B2) in specified vibronic states is reported. The O(1D)-atom yields below and above the dissociation limit (40973 cm?1) have been measured. The role played by the rotational excitation energy and the vibrational excitation modes in promoting the predissociation is discussed. |
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