Intermode energy transfer in vibrationally excited O3 |
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| Authors: | Kin-Kwok Hui David I. Rosen Terrill A. Cool |
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| Affiliation: | School of Applied and Engineering Physics, Cornell University, Ithaca, New York 14853, USA |
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| Abstract: | The laser excited fluorescence method has been employed to determine the rate constants for vibrational relaxation of the O3 (010), O3 (100) and O3 (001) levels at 298 K. The fluorescence observations from the O3 (010) level provide direct measurements of the rate for intermode vibrational energy transfer from the coupled ν1 and ν3 modes to the ν2 mode. The slowness of this process indicates the likelihood that the ν1 and/or ν3 modes (rather than the ν2 mode) play a predominant role in the laser enhanced reaction between O32 and NO at 298 K. |
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| Keywords: | To whom correspondence should be addressed |
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