Magnetic circular dichroism spectra of the methyl halides. Resolution of the n → σ* continuum |
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| Authors: | Aharon Gedanken Michael D Rowe |
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| Institution: | University of Southern California, Department of Chemistry, Los Angeles, California 90007, USA |
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| Abstract: | The MCD (magnetic circular dichroism) of CH3l, CH3Br and CH3Cl has been studied in the spectral region of the n → σ* continuum (3500-1700 Å). The MCD spectrum of CH3I makes it possible to resolve the three excited states contributing to the continuum. The peak energies and the oscillator strengths of the components are obtained. |
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