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From Containers to Catalysts: Supramolecular Catalysis within Cucurbiturils
Authors:Barry C Pemberton  Ramya Raghunathan  Sabine Volla  Jayaraman Sivaguru
Institution:Department of Chemistry and Biochemistry, North Dakota State University, 1231 Albrecht Blvd., Fargo, ND 58108‐6050 (USA), Fax: (+1)?701‐231‐8831
Abstract:Cucurbiturils are a family of molecular container compounds with superior molecular recognition properties. The use of cucurbiturils for supramolecular catalysis is highlighted in this concept. Both photochemical reactions as well as thermal transformations are reviewed with an eye towards tailoring substrates for supramolecular catalysis mediated by cucurbiturils.
Keywords:catalysis by confinement  cucurbiturils  molecular recognition  photocatalysis  supramolecular catalysis
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