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Magnetic susceptibility of ruthenium(III) in tris-ethylenediamine salts. Effect of outer sphere ligands |
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| Authors: | Henry J Peresie Joseph A Stanko Laxman N Mulay |
| Affiliation: | Departments of Chemistry and Solid State Science, The Pennsylvania State University, University Park, Pennsylvania 16802, USA |
| Abstract: | The paramagnetic susceptibility of Ru(III) in tris-ethylenediamine salts has been measured as a function of temperature. In all cases the iodide salt exhibits a greater susceptibility than the bromide salt. This difference may be attributed to a larger degree of temperature independent paramagnetism in the iodide complex due to the presence of low lying charge transfer states. |
| Keywords: | Address correspondence to this author at Department of Chemistry University of South Florida Tampa Florida 33620 USA |
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