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Complexes of Di‐ and Triazacrown Ethers with Heavy Metal Ions in Water Solution
Authors:Olga Fedorova  Yury Fedorov  Maxim Oshchepkov
Institution:1. A.?N. Nesmeyanov Institute of Organic Element Compounds of the Russian Academy of Sciences, Vavilova, 28, Moscow, 119991, GSP‐1, Russia;2. Mendeleyev University of Chemical Technology of Russia, Miusskaya sqr., 9, Moscow, 125047, Russia
Abstract:This research concerns the analysis of the metal ion binding of benzo‐ and pyridine‐azacrown ether compounds of different structures and sizes by potentiometric method. The ligands are able to form 1 : 1 complexes with heavy metal ions (Cu+2, Pb+2, Cd+2, Ag+, Ni+2, Zn+2) in water of middle or high stability. To understand the selectivity in cation binding, different factors were considered.
Keywords:Azacrown ether compounds  Complex formation  Potentiometric method  N/O ligands  Heavy metal ions
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