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X‐ray Absorption Spectroscopic,Crystallographic, Theoretical (DFT) and Chemical Evidence for a Chalcogen–Chalcogen Two‐Center/Three‐Electron Half Bond in an Unprecedented “Subselenide” Se23− Ligand |
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| Authors: | Dr Shu A Yao Prof Kyle M Lancaster Dr Andreas W Götz Prof Serena DeBeer Prof John F Berry |
| Institution: | 1. Department of Chemistry, University of Wisconsin–Madison, 1101 University Ave., Madison, WI 53706 (USA);2. Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, NY 14853 (USA);3. San Diego Supercomputer Center, University of California San Diego, La Jolla, CA 92093 (USA);4. Max‐Planck‐Institut für Bioanorganische Chemie, Stiftstrasse 34–36, 45470 Mülheim an der Ruhr (Germany) |
| Abstract: | |
| Keywords: | delocalized bonding nickel selenium two‐center/three electron half bond X‐ray spectroscopy |