The role of orbiting collisions in vibrational energy transfer |
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Authors: | Paul D. Gait |
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Affiliation: | Department of Chemistry, University of Chicago, Chicago, Illinois, USA |
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Abstract: | Using a simple model of molecular collisions under a spherically symmetric interaction, it is shown that orbiting collisions can make very large contributions to the inelastic cross sections of non-resonant processes. Calculations for the system HX + CO2(001) → HX(υ=1) + CO2(000), where X = F, Cl, I show good agreement with experimental results. |
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