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New Iridoid and Secoiridoid Glucosides from the Roots of Gentiana manshurica
Authors:Qing Liu  Gui‐Xin Chou  Zheng‐Tao Wang
Institution:1. Shanghai R&D Center for Standardization of Chinese Medicines, 199 Guo Shoujing Road, Zhangjiang Hi‐Tech Park, Shanghai 201203, P.?R. China;2. Key Laboratory of Standardization of Chinese Medicines, Ministry of Education, Institute of Chinese Materia Medica of Shanghai University of Traditional Chinese Medicine, Cai Lun Road 1200, Zhangjiang, Shanghai, 201203, P.?R. China, (phone: +86‐21‐51322507 (Z.‐T.?W.), +86‐21‐50271706 (G.‐X.?C.);3. fax: +86‐21‐51322519 (Z.‐T.?W.), +86‐21‐50271708 (G.‐X.?C.))
Abstract:One new iridoid glucoside, 4″‐Oβ‐D ‐glucosyl‐6′‐O‐(4‐Oβ‐D ‐glucosylcaffeoyl)linearoside ( 1 ), and two new secoiridoid glucosides, 6′‐O‐acetylsweroside ( 2 ) and 6′‐O‐acetyl‐3′‐O‐3‐(β‐D ‐glucopyranosyloxy)‐2‐hydroxybenzoyl]sweroside ( 3 ), were isolated from the dried roots of Gentiana manshurica (Gentianaceae), together with 11 known ones, including one iridoid glucoside, five secoiridoid glucosides, and five triterpenes. The structures of the new compounds were determined on the basis of detailed spectroscopic analyses and acidic hydrolysis.
Keywords:Gentiana manshurica  Iridoid glucoside  Secoiridoid glucosides  Glucosides
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