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Effect of the Dispersing Agent on the Electrochemical Response of Glassy Carbon Electrodes Modified with Dispersions of Carbon Nanotubes
Authors:Karina González‐Segura  Paulina Cañete‐Rosales  Rodrigo del Rio  Claudia Yáñez  Nancy F. Ferreyra  Gustavo A. Rivas  Soledad Bollo
Affiliation:1. Laboratorio de Bioelectroquímica, Facultad de Ciencias Químicas y Farmacéuticas, Universidad de Chile, Santiago, Chile;2. INFIQC. Departamento de Físico Química. Facultad de Ciencias Químicas, Universidad Nacional de Córdoba. Ciudad Universitaria. 5000, Córdoba, Argentina
Abstract:The electrochemical response of a glassy carbon electrode modified with carbon nanotubes (CNT) dispersed in two solvents, water and DMF, and two polymers, chitosan and Nafion is reported. The films were homogeneous when the dispersing agent was water or DMF. In the case of polymers, the surfaces present areas with different density of CNTs. A more sensitive electrochemical response was obtained when CNTs are dispersed in the solvents. In the case of CNT dispersed with polymers, the nature of the polymer demonstrated to be a critical parameter not only for dispersing the nanotubes but also for the electrochemical activity of the resulting electrodes.
Keywords:Carbon nanotubes  Scanning electrochemical microscopy  Chitosan  Nafion  Hydrogen peroxide sensors
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