Synthesis,crystal structure and magnetic properties of a new 3D coordination polymer constructed by Co(II) with pyridine-3,4-dicarboxylate and 4,4’-bipyridine |
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| Authors: | Zheng-Bo Han Zhen-Ning Lou Yu-Chun Jiang Li-Tian Zhang Li Liu |
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| Affiliation: | (1) School of Chemical Science and Engineering, Liaoning University, Shenyang, 110036, P.R. China;(2) School of Materials and Metallurgy, Northeastern University, Shenyang, 110004, P.R. China |
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| Abstract: | A metal-organic framework, [Co2(pydc)2(bpy)2] n · 2nH2O (1) (H2pydc = pyridine-3,4-dicarboxylic acid, bpy = 4,4′-bipyridine), was synthesized under hydrothermal conditions. X-ray diffraction experiments reveal that (1) exhibits a chiral 3D metal-organic framework, which represents the rare example of 3D chiral coordination polymers containing two kinds of organic ligands. Temperature-dependent magnetic susceptibility for (1) was also studied. Electronic Supplementary Material Supplementary material is available to authorised users in the online version of this article at . |
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