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Kinetic analysis of thermogravimetric data |
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| Authors: | J. Zsakó I. Ganescu Cs. Várhelyi L. Chirigiu |
| Affiliation: | (1) Chemistry Department, Babe!["Scedil"]("/content/m8w0126063601710/xlarge350.gif") -Bolyai University, 3400 Cluj;(2) Chemistry Department, Craiova University, 1100 Craiova, Romania |
| Abstract: | Thermal decomposition of 6 complexes of the type AH[Cr(NCS)4 (am)2]· nH2O is studied with derivatograph. The formation of Cr(NCS)3 as a labile intermediate is presumed. For some decomposition stages kinetic parameters are derived. The kinetic compensation effect is discussed. |
| Keywords: | chrom(III)-complexes isokinetic relations non-isothermal kinetics thermal decomposition |
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