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Modification of fullerene C60 by phosphorylated diazo compounds
Authors:Romanova  I. P.  Musina  E. I.  Nafikova  A. A.  Zverev  V. V.  Yakhvarov  D. G.  Sinyash  O. G.
Affiliation:(1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088 Kazan, Russian Federation
Abstract:New representatives of phosphorylated methanofullerenes were prepared by the reactions of [60]fullerene with O,O-diethyl agr-diazoethyl- and O,O-diethyl agr-diazobenzylphosphonates. Electrochemical reduction of the above-mentioned products proceeded stepwise and reversibly.
Keywords:[60]fullerene  O,O-diethyl   /content/jj68556v228540r9/xxlarge945.gif"   alt="  agr"   align="  BASELINE"   BORDER="  0"  >-diazoethyl- and O,O-diethyl   /content/jj68556v228540r9/xxlarge945.gif"   alt="  agr"   align="  BASELINE"   BORDER="  0"  >-diazobenzylphosphonates  phosphorylated methanofullerenes  electrochemistry  quantum-chemical calculations
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