| Synthesis and Crystal Structure of Tetrabonzoato Bis （2－Aminothiazol） Dicopper（Ⅱ） |
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| 引用本文： | Wang Dong-Mei, Hou Yi-Min, Yang RuiNa, Hu Xiao-Yuan,Xuo Bao-Yu, Jin DouMan(Henan Institute of Chemistry,Zhengzhou 450003)Chen Liao-Rong,Luo Bao-Sheng(Wuhan University,Wuhan 430072). Synthesis and Crystal Structure of Tetrabonzoato Bis （2－Aminothiazol） Dicopper（Ⅱ）[J]. 结构化学, 1995, 0(4) |
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| 作者姓名： | Wang Dong-Mei Hou Yi-Min Yang RuiNa Hu Xiao-Yuan Xuo Bao-Yu Jin DouMan(Henan Institute of Chemistry Zhengzhou 450003)Chen Liao-Rong Luo Bao-Sheng(Wuhan University Wuhan 430072) |
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| 作者单位： | Wang Dong-Mei; Hou Yi-Min; Yang RuiNa; Hu Xiao-Yuan;Xuo Bao-Yu; Jin DouMan(Henan Institute of Chemistry，Zhengzhou 450003)Chen Liao-Rong，Luo Bao-Sheng(Wuhan University，Wuhan 430072) |
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| 摘 要： | ＳｙｎｔｈｅｓｉｓａｎｄＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆＴｅｔｒａｂｏｎｚｏａｔｏＢｉｓ（２－Ａｍｉｎｏｔｈｉａｚｏｌ）Ｄｉｃｏｐｐｅｒ（Ⅱ）ＷａｎｇＤｏｎｇ－Ｍｅｉ；ＨｏｕＹｉ－Ｍｉｎ；ＹａｎｇＲｕｉＮａ；ＨｕＸｉａｏ－Ｙｕａｎ；ＸｕｏＢａｏ－...
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Synthesis and Crystal Structure of Tetrabonzoato Bis(2-Aminothiazol) Dicopper(Ⅱ) |
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| Wang Dong-Mei, Hou Yi-Min, Yang RuiNa, Hu Xiao-Yuan,Xuo Bao-Yu, Jin DouMan. Synthesis and Crystal Structure of Tetrabonzoato Bis(2-Aminothiazol) Dicopper(Ⅱ)[J]. Chinese Journal of Structural Chemistry, 1995, 0(4) |
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| Authors: | Wang Dong-Mei Hou Yi-Min Yang RuiNa Hu Xiao-Yuan Xuo Bao-Yu Jin DouMan |
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| Abstract: | Reaction of Cu with dibenzovi peroxide, 2-aminothiazol gave a binuclear complex [Cu_2 (C_6H_5COO)_4(C_3H_4N_2S)_2]. Crystal of the title compound is monoclinic system space group P2_1/n , M_r = 807. 84 with cell parameters a= 10. 685 ( 1 ), b=19. 028(6), c=17. 046(9) , β=96. 49(33)￣°, Z=4, V=3443. 4, D_c=1. 565 g/cm￣-3, μ= 14. 078 cm￣-1, F(000)= 824. The final refinement with 3429 observed reflections is converged with R= 0. 046 and R_w=0. 053. X-ray crystal structure analysis revealed that each copper ion is coordinated by four bridging birfentate benzoate ligandsand one Zaminothiazol to form a binuclear molecule. In the crvstal, there are intramolecular hydrogen bonds N (1)- H ( 1 )-O(4) and N (3)- H (3)-O(1) with NO distance of 3. 005, N-H-O angle of 131. 9°. |
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| Keywords: | binuclear copper complex oxidative addition crystal structure |
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