Synthesis of Polynuclear Organometallic and o-Quinone Compounds by Direct Metal Oxidation in Nonaqueos Solutions |
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Authors: | Piskunov A V Maslennikov S V Spirina I V Maslennikov V P |
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Institution: | (1) Scientific Research Institute of Chemistry, Lobachevskii State University, Nizhnii Novgorod, Russia |
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Abstract: | A review of papers concerned with the synthesis of polynuclear organometallic compounds by direct metal oxidation with organoelemental halides is presented. The effect of solvent nature on the rate of metal oxidation in nonaqueous solutions is considered. The mechanism of metal oxidation with o-quinone in aprotic dipolar solvents is suggested. |
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