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Stereochemical control of H2O2 dismutation by Hangman porphyrins
Authors:Rosenthal Joel  Chng Leng Leng  Fried Stephen D  Nocera Daniel G
Affiliation:Department of Chemistry, 6-335, Massachusetts Institute of Technology, Cambridge, MA 02139, USA.
Abstract:Incorporation of a disparate set of aryl groups appended to the meso-positions of Hangman porphyrin xanthene architectures dramatically impacts the ability of such systems to catalyze the disproportionation of H2O(2)via the catalase reaction.
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