Synthesis and characterization of cyclopentadienyl transition metal halides,part I,vanadium halides |
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Authors: | Moisés Morán |
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Institution: | (1) Departamento de Quimica Inorgánica Universidad Autónoma de Madrid, Cantoblanco, Madrid, Spain |
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Abstract: | Summary Reactions between -Cp2V and PX3 (X=Cl, Br or I) yield the corresponding dihalogenated derivatives -Cp2VX2 (X=Cl, Br or I). The oxidative addition of ICl and IBr to -Cp2V gives mixed halogenated derivatives -Cp2VIX (X=Cl or Br). All the compounds have been characterized by elemental analyses, magnetic moment measurements and i.r. and e.p.r. spectra. |
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