A free radical initiated optically active vinyl polymer with memory of chirality after removal of the inducing stereogenic center |
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Authors: | Yu Zhenning Wan Xinhua Zhang Hailiang Chen Xiaofang Zhou Qifeng |
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Affiliation: | College of Chemistry & Molecular Engineering, Peking University, Beijing 100871, China. |
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Abstract: | Free radical polymerization of (+)-2,5-bis[4'-((S)-2-methylbutyloxy)phenyl]styrene yields a chiral polymer with memory of optical activity after the initial stereogenic center in the side group of the monomer is chemically removed. |
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