A novel type of phosphide: synthesis and X-ray crystal structure analysis of (tBu3Si)3P4Li3 |
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| Authors: | Lerner Hans-Wolfram Wagner Matthias Bolte Michael |
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| Affiliation: | Institut für Anorganische Chemie, Johann Wolfgang Goethe-Universit?t Frankfurt am Main, Marie-Curie-Strasse 11, 60439 Frankfurt am Main, Germany. |
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| Abstract: | The tetraphosphides (tBu3Si)3P4M3 (M = Li, Na) and (tBu2PhSi)3P4Na3 have been synthesized in high yield from the reaction of 3 equivalents of the silanides tBu3SiM (M = Li, Na) and tBu2PhSiNa with P4 in benzene. (tBu3Si)3P4M3 (M = Li, Na) are transformed into the unsaturated triphosphides (tBu3Si)2P3M (M = Li, Na) and tBu3SiPM2 in tetrahydrofuran at ambient temperature. |
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