| 共轭二茂铁席夫碱配合物的制备和电化学性质研究 |
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| 引用本文： | 毛薇莉,李一志,苏扬,田正芳,章文伟.共轭二茂铁席夫碱配合物的制备和电化学性质研究[J].无机化学学报,2007,23(7):1201-1205. |
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| 作者姓名： | 毛薇莉 李一志 苏扬 田正芳 章文伟 |
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| 作者单位： | 南京大学配位化学国家重点实验室,南京大学配位化学研究所,南京大学化学化工学院,南京,210093 |
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| 基金项目： | 教育部留学回国人员科研启动基金;国家自然科学基金 |
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| 摘 要： | 合成了2个共轭二茂铁席夫碱配合物，用元素分析、红外光谱、紫外光谱、核磁共振等对它们进行了表征及电化学性质 研究，并用X射线衍射测定了它们的晶体结构。配合物1存在反演中心，其晶体属单斜晶系，P21/c空间群。晶体学数据为：a=1.148 5(2) nm，b=0.857 75(17) nm，c=1.194 4(2) nm，β=99.980(5)°,V=1.158 8(4) nm3,Z=2，μ=1.499 mm-1,Dc=1.562 g·cm-3，R1=0.068 9，wR2=0.128 0。
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| 关 键 词： | 二茂铁 席夫碱 共轭配合物 电化学性质 |
| 文章编号： | 1001-4861（2007）07-1201-05 |
| 修稿时间： | 2007-03-282007-05-10 |
Study on the Synthesis and Electrochemical Properties of Conjugated Complexes Containing Ferrocenyl and Schiff-base Group |
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| MAO Wei-Li,LI Yi-Zhi,SU Yang,TIAN Zheng-Fang and ZHANG Wen-Wei.Study on the Synthesis and Electrochemical Properties of Conjugated Complexes Containing Ferrocenyl and Schiff-base Group[J].Chinese Journal of Inorganic Chemistry,2007,23(7):1201-1205. |
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| Authors: | MAO Wei-Li LI Yi-Zhi SU Yang TIAN Zheng-Fang and ZHANG Wen-Wei |
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| Institution: | Sate Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093,Sate Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093,Sate Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093,Sate Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 and Sate Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 |
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| Abstract: | |
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| Keywords: | ferrocene Schiff-base conjugated complex electrochemical property |
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