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Chemical constituents isolated from Zygophyllum melongena Bunge growing in Mongolia
Authors:Chunsriimyatav Ganbaatar  Margit Gruner  Jigjidsuren Tunsag  Dulamjav Batsuren  Batsuren Ganpurev  Lkhamjav Chuluunnyam
Institution:1. Department of Chemistry, Technische Universit?t Dresden, Dresden, Germany;2. Institute of Chemistry and Chemical Technology, Mongolian Academy of Sciences, Ulaanbaatar, Mongolia;3. Institute of Chemistry and Chemical Technology, Mongolian Academy of Sciences, Ulaanbaatar, Mongolia;4. School of Medicine, Mongolian National University of Medical Sciences, Ulaanbaatar, Mongolia
Abstract:We report the first investigation of the chemical constituents of Zygophyllum melongena Bunge, a species growing in Mongolia. The quinovic acid glycosides 3-O-(β-D-glucopyranosyl)quinovic acid and 3-O-(β-D-glucopyranosyl)quinovic acid (28→1)-(β-D-glucopyranosyl) ester were identified in the chloroform fraction along with the flavonoid glycoside astragalin. The n-butanol fraction contained (+)-D-pinitol as the major component, a cyclitol with anti-diabetic properties. The structures of the isolated natural products were confirmed using ESI-MS and NMR spectroscopy (1H, 13C, COSY, HSQC, HMBC, NOESY and ROESY). This is the first report of the isolation of (+)-D-pinitol from the genus Zygophyllum.
Keywords:Astragalin  Zygophyllum melongena  NMR spectroscopy  quinovic acid  pinitol
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