The synthesis and spectral characterization of novel nitrodiene compounds from thiols

Novel S-, S,S- and S,O-substituted nitrodiene compounds were synthesized from the reactions of 2-nitro-pentachloro-1,3-butadiene (1) and various thiols in different solvent media. The N,S-substituted nitrodienes also were achieved by the reactions of S-substituted nitrodienes with using morpholine, piperidine and piperazine derivatives. All of the new compounds were characterized by elemental analysis, UV-VIS, FT-IR, ¹H-NMR, NMR and mass spectroscopy.