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Addition of various unsaturated alcohols to sulfonylisocyanate derivatives: Synthesis of new unsaturated N-sulfonyl carbamates
Authors:Ahlem Radhouani  Mohamed Beji
Affiliation:1. Laboratory of Structural Organic Chemistry, Department of Chemistry, Faculty of Sciences of Tunis, Tunis, Tunisiahalouma163@yahoo.fr;3. Laboratory of Structural Organic Chemistry, Department of Chemistry, Faculty of Sciences of Tunis, Tunis, Tunisia
Abstract:The synthesis of new unsaturated N-sulfonylcarbamates by the addition of unsaturated alcohols to aroxy(alkoxy)sulfonylisocyanates is reported. The reaction is carried out at room temperature in the presence or absence of solvent, depending on the nature of the starting alcohol. The products were obtained in good yields and characterized with IR, 1H, and 13C NMR and HRMS analyses.
Keywords:Aroxy(alcoxy)sulfonylisocyanates  unsaturated alcohols  cholesterol  allyl alcohols  unsaturated N-sulfonylcarbamates
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