| 停流分光光度法研究铁卟啉与肼反应动力学 |
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| 引用本文： | 钟新华,黄杰生,周永洽,林华宽,卜显和,申泮文.停流分光光度法研究铁卟啉与肼反应动力学[J].无机化学学报,1996,12(2):126-129. |
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| 作者姓名： | 钟新华 黄杰生 周永洽 林华宽 卜显和 申泮文 |
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| 作者单位： | 南开大学化学系，南开大学化学系，南开大学化学系，南开大学化学系，南开大学化学系，南开大学化学系 天津，300071，天津，300071，天津，300071，天津，300071，天津，300071，天津，300071 |
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| 基金项目： | 天津市 2 1世纪青年基金资助课题 |
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| 摘 要： | 用停流分光光度法研究了氯代四苯基卟啉铁 ( ) Fe T(p- X) PPCl,X=H,CH3 ]与肼在二氯甲烷溶液中的反应动力学 ,求得了不同温度下反应的速率常数及活化参数 ,初步探讨了反应机理。
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| 关 键 词： | 铁卟啉 肼 动力学 停流分光光度法 |
| 收稿时间： | 1995/3/22 0:00:00 |
STUDY ON KINETICSOF REACTION BETWEEN IRON PORPHYRIN AND HYDRAZINE HYDRATE BY STOPPED-FLOW METHOD |
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| Zhoug Xinhu,Huang Jieshen,Zhou Yongqi,Lin Huakuan,Bu Xianhe and Shen Panwen.STUDY ON KINETICSOF REACTION BETWEEN IRON PORPHYRIN AND HYDRAZINE HYDRATE BY STOPPED-FLOW METHOD[J].Chinese Journal of Inorganic Chemistry,1996,12(2):126-129. |
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| Authors: | Zhoug Xinhu Huang Jieshen Zhou Yongqi Lin Huakuan Bu Xianhe and Shen Panwen |
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| Institution: | Department of Chemistry, Nankai University, Tianjin 300071,Department of Chemistry, Nankai University, Tianjin 300071,Department of Chemistry, Nankai University, Tianjin 300071,Department of Chemistry, Nankai University, Tianjin 300071,Department of Chemistry, Nankai University, Tianjin 300071 and Department of Chemistry, Nankai University, Tianjin 300071 |
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| Abstract: | The kinetics of reaction between chloroiron tetraphenylprophyrin Fe T(p- X) PPCl(X= H,CH3 ) and hydrazine hydrate in dichloromethane solution was investigated.The rate constant of the reaction at various temperature and active parameters were obtained. The mechanism of the reaction was explored. |
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| Keywords: | iron porphyrin hydrazine kinetics stopped- flow method |
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