| 间-四(4-羟基苯基)卟啉金属配合物的固相合成研究 |
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| 引用本文： | 张银汉,刘允平,倪其道,宋子台. 间-四(4-羟基苯基)卟啉金属配合物的固相合成研究[J]. 无机化学学报, 1996, 12(3): 333-336 |
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| 作者姓名： | 张银汉 刘允平 倪其道 宋子台 |
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| 作者单位： | 中国科学技术大学应用化学系, 合肥230026,中国科学技术大学应用化学系, 合肥230026,中国科学技术大学应用化学系, 合肥230026,中国科学技术大学应用化学系, 合肥230026 |
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| 摘 要： | 本文研究了在固相条件ＴＨＰＰ与金属铜或铅配合物的合成，反应温度和引发剂对反应速率影响较大。合成产物的可见光谱、红外光谱和荧光光谱与液相条件下合成的样品一致。
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| 关 键 词： | 卟啉 固相反应 铜 铅 配合物 |
| 收稿时间： | 1995-10-10 |
SYNTHESIS OF meso-TETRA(4-HIYDROXYPHENYL) PORPHYRIN WITH COPPER AND LEAD COMPLEXES BY SOLID STATE REATION |
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| Zhang Yinhan,Liu Yunping,Ni Qidao and Song Zital. SYNTHESIS OF meso-TETRA(4-HIYDROXYPHENYL) PORPHYRIN WITH COPPER AND LEAD COMPLEXES BY SOLID STATE REATION[J]. Chinese Journal of Inorganic Chemistry, 1996, 12(3): 333-336 |
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| Authors: | Zhang Yinhan Liu Yunping Ni Qidao Song Zital |
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| Affiliation: | Department of Applied Chemistry, University of Science and Technology of China, Hefei 230026,Department of Applied Chemistry, University of Science and Technology of China, Hefei 230026,Department of Applied Chemistry, University of Science and Technology of China, Hefei 230026 and Department of Applied Chemistry, University of Science and Technology of China, Hefei 230026 |
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| Abstract: | Synthesis of MTHPP(M=Cu, Pb) complexes by solid state reaction at room temperature have been studied. Reaction temperature and initiator affect reaction rate. The composition and conformation of products are the same as that synthesized in liquid state characterized with element analysis, IR, fluorescence. |
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| Keywords: | porphyrin complex solid state reaction copper lead |
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