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Wade规则在稠合型硼烷等中的应用
引用本文:金成树. Wade规则在稠合型硼烷等中的应用[J]. 化学研究与应用, 2000, 12(5): 482-486
作者姓名:金成树
作者单位:黑龙江省绥化师范专科学校实验中心,黑龙江,绥化,152000
基金项目:黑龙江省教委科研项目,,
摘    要:本文把Wade规则推广应用于稠合型硼烷和稠合型金属碳硼烷中,导出计算它们价电子数(NVE)的公式。对于稠合型硼烷,本文公式与唐敖庆等的拓扑结构规则的计算结果相同。但本文公式的适用范围比上述两个规则广。

关 键 词:Wada规则 稠合型硼烷 稠合型金属碳硼烷 NVE
修稿时间:2000-01-04

APPLICATION OF WADE'S RULE TO JOINED-TYPE BORANES AND SOME OTHER COMPOUNDS
JIN Cheng-shu. APPLICATION OF WADE'S RULE TO JOINED-TYPE BORANES AND SOME OTHER COMPOUNDS[J]. Chemical Research and Application, 2000, 12(5): 482-486
Authors:JIN Cheng-shu
Abstract:The extended application of Wade's rule to joined type boranes and metallocarboranes was discussed in this article.A new formula for calculating the number of valence electrons was derived.The calculated results of joined type boranes are in agreement with that obtained from the topological structure rule proposed by Tang Au chin et al.,but the new formula can be used in a more wide range.
Keywords:Wade's rule  joined type boranes  joined type metallocarboranes  metallorganic compounds
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