A hydroxyaminophosphane derived from 2-imidazolidone and its unusual structure in solution |
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| Authors: | Olaf Kühl Waltraud Heiden |
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| Institution: | (1) Institute of Biochemistry, University of Greifswald, D-17489 Greifswald, Germany |
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| Abstract: | A novel hydroxyamino phosphane was synthesised through the reaction of 2-imidazolidinone with ClPPh2 and subsequently reaction
of the resulting bisphosphino derivative with the Grignard reagent BrMgC5H11. The interaction of the pentyl substituent with one of the two phosphino groups and the structure in solution is shown by
multinuclear NMR-spectroscopy..
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| Keywords: | Grignard reaction Hydroxyaminophosphane Phosphane Reduction „ Through-space” -coupling |
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