Highly Selective Sorption and Luminescent Sensing of Small Molecules Demonstrated in a Multifunctional Lanthanide Microporous Metal–Organic Framework Containing 1D Honeycomb‐Type Channels |
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| Authors: | Huanhuan Li Dr. Wei Shi Kaina Zhao Zheng Niu Huimin Li Prof. Dr. Peng Cheng |
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| Affiliation: | Department of Chemistry and Key Laboratory of Advanced Energy Materials Chemistry (MOE), Nankai University, Tianjin 300071 (P.R. China), Fax: (+86)?22‐23502458 |
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| Abstract: | A rare, robust microporous lanthanide metal–organic framework with 1D honeycomb‐type channels is presented. Excellent adsorption capabilities for N2, H2, and CO2 and significant selective sorption of CO2 over N2 and CH4 were observed. Moreover, the guest‐dependent luminescent behavior of these lanthanide materials shows a potential use for the sensing of small‐molecule pollutants such as benzene and acetone. |
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| Keywords: | adsorption lanthanides luminescence metal– organic frameworks sensors |
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