Second harmonic generation properties of Ca3(O3C3N3)2 ‐Sr3(O3C3N3)2 solid solutions |
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| Authors: | Markus Kalmutzki,Xiao Wang,Alfred J. Meixner,Hans‐Jü rgen Meyer |
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| Abstract: | Solid solutions of the second harmonic generation (SHG) materials Ca3(O3C3N3)2 (CCY) and Sr3(O3C3N3)2 (SCY) were prepared via exothermic solid state metathesis reactions from appropriate amounts of the corresponding metal chlorides and potassium cyanate at 525 °C. The change in SHG intensity caused by the successive cation substitution is reported. Differential thermal analyses are used to explore the SCY–K(OCN) phase diagram as a medium for the growth of SCY crystals. |
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| Keywords: | solid state metathesis cyanurate nonlinear optics phase diagram |
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