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Synthesis and Characterization of MoFe3S4 and Mo2Fe2S4 Single Cubanes
Authors:Markos Koutmos  Irene P Georgakaki  Panagiotis Tsiolis  Dimitri Coucouvanis Prof
Institution:Ann Arbor/USA, University of Michigan
Abstract:The synthesis of multimetallic M/S clusters by the reductive coupling of dimeric building blocks appears to be of general utility. In this paper we describe the synthesis and characterization of new single cubanes with cores such as Mo2Fe2S4]2+ and MoFe3S4]3+,2+.
Keywords:Nitrogenase  Cluster compounds (Mo/Fe/S)  Cubanes
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