Pertechnetyl Fluorosulfate, [TcO3]+[SO3F]− |
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| Authors: | Joanna Supeł Adelheid Hagenbach U. Abram Konrad Seppelt Prof. Dr. |
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| Affiliation: | Berlin, Freie Universit?t, Institut für Chemie, Anorganische und Analytische Chemie |
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| Abstract: | A one step synthesis of [TcO3]+[SO3F]? is reported. The compound is volatile at room temperature and has according to calculations a tetrahedral coordination around Tc and a monodentate SO3F group. In the solid state the [SO3F]? anion bridges three [TcO3]+ cations, and vice versa. Space group P21/c, Z = 4, lattice dimensions at 173 K: a = 695.4(11), b = 808.6(12), c = 893.3(14) pm, β = 97.36(8)°. |
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| Keywords: | Technetium Fluorosulfate |
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