Pressure‐induced polymerization of tetraethylene glycol dimethacrylate |
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Authors: | Kamil Kaminski Marian Paluch R. Wrzalik Jerzy Ziolo Radoslav Bogoslovov C. Michael Roland |
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Affiliation: | 1. Institute of Physics, Silesian University, Uniwersytecka 4, 40‐007 Katowice, Poland;2. Chemistry Division, Code 6120, Naval Research Laboratory, Washington, DC 20375‐5342 |
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Abstract: | The polymerization and crosslinking of tetraethylene glycol dimethacrylate were induced by high pressure. The product was analyzed by both swelling experiments and broadband dielectric spectroscopy to determine the structure, with IR measurements used to follow the extent of reaction and its temperature dependence. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 3795–3801, 2008 |
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Keywords: | acrylates crosslinking degree of polymerization (DP) dielectric properties molecular dynamics polymerization pressure swelling |
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