The copolymerization behavior of the acidic monomer 2‐acrylamido‐2‐methyl‐1‐propanesulfonic acid (APSA) and 1‐vinylimidazole in inverse miniemulsion was studied under various conditions. Initially, different surfactants and surfactant concentrations were investigated. After determining a suitable composition of the miniemulsion, changes in the reaction behavior under different pH values and monomer feed compositions were studied. The highest polymerization rates could be produced under neutral conditions over all monomer feed ratios. The addition of acid or base to change the pH value of the monomer mixture also has influence on the polymers obtained. The thermal stability, rheological stiffness and intrinsic viscosity increase when Na‐APSA is incorporated.