Synthesis,Crystal Structure and Magnetism Characterization of Two Coordination Polymers based on Ni(2‐mpac)2(H2O)2 as Molecular Building Block |
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Authors: | San‐Ping Chen Guang Fan Sheng‐Li Gao Prof. |
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Affiliation: | Xi'an, Shaanxi / P. R. China, Northwest University, Department of Chemistry, Shaanxi Key Laboratory of Physico‐Inorganic Chemistry |
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Abstract: | Taking Ni(2‐mpac)2(H2O)2 as molecular building block, two novel coordination polymers with the formula of [Ni(2‐mpac)2(4,4′‐bpy)·(4,4′‐bpy)]n ( 1 ) and [Ni(2‐mpac)2(py)·4H2O]n ( 2 ) (2‐mpac = 5‐methyl‐2‐pyrazinecarboxylic acid; 4,4′‐bpy = 4,4′‐bipyridine; py = pyrazine) have been synthesized and structurally characterized by X‐ray single crystal diffraction method. In addition, elemental analysis, IR and magnetism characterization are presented. |
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Keywords: | Coordinationpolymers Molecular building block Magnetic properties |
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