Cerium Complex with Four Types of Ligands: (NH4)6[Ce(H2W12O40)(C4H2O4)(NO3)(H2O)3] |
| |
| Authors: | Dongmei Shi Yaguang Chen Dr Haijun Pang |
| |
| Institution: | Changchun / P. R. China. Northeast Normal University, College of Chemistry, Key Laboratory of Polyoxometalates Science of Ministry of Education |
| |
| Abstract: | A novel polymer (NH4)6Ce(H2W12O40)(C4H2O4)(NO3)(H2O)3] ( 1 ) has been constructed at room temperature and characterized by single crystal X‐ray structural analyses, elemental analyses, cyclic voltammetry, IR spectrum, and thermogravimetry. X‐ray structural analysis reveals that through the W–Ot′–Ce–Ob–W linkages a one‐dimension infinitely linear chain with alternating cations and anions is formed. 1 represents the first characterized compound that the Ce3+ ions are coordinated by four different types of ligands, and maleinate as ligands in constructing LnPOM architecture. |
| |
| Keywords: | Cerium Chain structure Polyoxometalates Maleinate |
|
|
