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Synthesis and characterization of dual‐responsive micrometer‐sized core‐shell composite polymer particles
Authors:M. Ashraful Alam  M. A. Jalil Miah  Hasan Ahmad
Affiliation:Department of Chemistry, Rajshahi University, Rajshahi 6205, Bangladesh
Abstract:Dual‐responsive micrometer‐sized core‐shell composite polymer particles were prepared by dispersion polymerization followed by seeded copolymerization. Polystyrene (PS) particles prepared by dispersion polymerization were used as core particles. N‐isopropyl acrylamide (NIPAM) and methacrylic acid (MAA) were used to induce dual‐responsive that is thermo‐ and pH‐responsive properties in the shell layer of composite polymer particles, prepared by seeded copolymerization with PS core particles. Temperature‐ and pH‐dependent adsorption behaviors of some macromolecules on composite polymer particles indicate that produced composite polymer particles exhibit dual‐responsive surface properties. Copyright © 2007 John Wiley & Sons, Ltd.
Keywords:composite polymer  dual‐responsive  adsorption behavior  hydrophilic
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