Synthesis of chalcone‐based fluorescent polymers: Diels‐Alder reaction of chalcones and their polymerization through ROMP |
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Authors: | R Kamakshi B S R Reddy |
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Institution: | Industrial Chemistry Laboratory, Central Leather Research Institute, Adyar, Chennai 600 020, India |
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Abstract: | Ring opening metathesis polymerization (ROMP) was carried out on Diels‐Alder adducts formed from reactions between chalcones and cyclopentadiene. Most of the chalcones gave predominantly endo‐adducts and the exo‐adducts were obtained in good yields from reacting cyclopentadiene with furfurylidine acetone and N,N,diethylaminobenzylidine‐(4‐hydroxy)acetophenone. These exo‐adducts were subjected to ROMP using Grubbs catalyst, bis(tricyclohexylphosphine)benzylidinedichloride. The monomers and polymers were characterized using spectroscopic techniques like FT‐IR, 1HNMR. The polymers were characterized using TGA, DSC, and GPC. The polymers were found to possess fluorescent properties and poly2‐(4‐diethylamino)phenyl‐3,5‐divinylcyclopentyl](4‐hydroxyphenyl) methanone was found to have good emissive property at two wavelengths. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 1521–1531, 2008 |
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Keywords: | Diels‐Alder polymers fluorescence ROMP |
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