Synthesis and thiol–ene photopolymerization of allyl‐ether functionalized dendrimers |
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Authors: | Camilla Nilsson Neil Simpson Michael Malkoch Mats Johansson Eva Malmström |
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Affiliation: | Department of Fibre and Polymer Technology, School of Chemical Science and Engineering, Royal Institute of Technology, Teknikringen 56‐58, SE‐100 44 Stockholm, Sweden |
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Abstract: | Well‐defined, allyl‐ether functional, first‐generation dendrimers have been synthesized. The convergent growth approach was utilized, using the anhydride of the allyl‐ether terminated building block. Three different core moieties were used: trimethylolpropane, trisphenol, and ditrimethylolpropane. The coupling reactions proceeded in good yields and all compounds were characterized by NMR, MALDI‐TOF, and SEC. The allyl‐terminated dendrimers were crosslinked by thiol–ene chemistry, using a multifunctional thiol, TriThiol, to give clear and smooth films. The photopolymerization was conducted in the presence of a photoinitiator, Irgacure 651, and no traces of either allyl‐ether groups or thiols were observed by FT‐Raman after cure. All crosslinked films were characterized with respect to mechanical (DMA) and thermal (DSC) properties. It was found that homogeneous networks were formed and that the core functionality and structure had little effect on the network properties. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 1339–1348, 2008 |
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Keywords: | crosslinking dendritic allyl‐ether thermosets thiol– ene photopolymerization viscoelastic properties |
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