A Novel Phase‐Transfer Catalyst: Monomeric Copper(II) Coordination Compound |
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| Authors: | Tian Hang Qiong Ye Ren‐Gen Xiong Prof |
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| Institution: | Nanjing / P. R. China, Southeast University, Ordered Matter Science Research Center |
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| Abstract: | The Copper(II) complex benzylcinchonidinium trichlorocuprate(II) ( 1 ) was obtained by the thermal treatments of CuCl2 with benzylcinchonidinium chloride ( L1 ) in Pyrex tubes. The enantioselective efficiency of 1 studied by alkylation reaction of N‐(diphenylmethylene)glycine tert‐butyl ester ( L2 ) is similar to that of normal benzylcinchonidinium chloride ( L1 ). |
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| Keywords: | Copper Chiral phase‐transfer catalyst Crystal structure |
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