[Cp2TiNi(S2N2)2] – The First Organometallic Derivative of [Ni(S2N2H)2] |
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| Authors: | Frank T Edelmann Prof Dr Steffen Blaurock Volker Lorenz Tristram Chivers Prof Dr |
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| Institution: | 1. Magdeburg / Germany, Chemisches Institut der Otto‐von‐Guericke‐Universit?t;2. 2500 University Drive NW, Calgary, AB T2N 1N4 / Canada |
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| Abstract: | The synthesis and structural characterization of the first organometallic derivative of Ni(S2N2H)2] ( 1 ) are reported. Treatment of K2Ni(S2N2)2] ( 2 ) with stoichiometric amounts of Cp2TiCl2] in boiling toluene afforded black, crystalline Cp2TiNi(S2N2)2] ( 3 ) in 50 % yield. According to a single‐crystal X‐ray diffraction study, the novel heterobimetallic complex 3 comprises a nearly planar TiNi(S2N2)2 arrangement. The Ti···Ni separation in 3 is 2.8348(5) Å, a value that is typical for bridged early‐late heterobimetallic complexes. |
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| Keywords: | Nickel Titanium Sulfur‐nitrogen‐ligands Heterobimetallic complexes Crystal structure |
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