Solvothermal Synthesis,Crystal Structure and Properties of a New Organic Templated Lanthanum Sulfate [C4N3H16][La(SO4)3(H2O)] |
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| Authors: | Yalin Zhu Guangpeng Zhou Yan Xu Dunru Zhu Xuefang Zheng |
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| Institution: | 1. Dalian Liaoning /P.R. China, Liaoning Normal University, Institute of Functionalized Chemistry Materials, Faculty of Chemistry and Chemical Engineering;2. Nanjing 210009, P. R. China, Nanjing University of Technology, Department of Chemistry, College of Chemistry and Chemical Engineering;3. Dalian Liaoning /P.R. China, Liaoning Key Laboratory of Bio‐Organic Chemistry |
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| Abstract: | A new organic templated lanthanum sulfate C4N3H16]La(SO4)3(H2O)] ( 1 ) has been solvothermally synthesized by using n‐butanol as solvent. The colorless block crystals were characterized by IR, TGA, ICP, and XRD. The structure was determined by single‐crystal X‐ray diffraction: Monoclinic, P21/c, a = 10.8878(19), b = 15.478(3), c = 9.9639(18) Å, β = 114.062(2)°, V=1533.2(5) Å3, Z = 4]. Crystal structure analysis shows that the one dimensional chain of 1 consists of the LaO9 polyhedra and the sulfate groups. Coordination water molecules link adjacent chains by using hydrogen bonds to generate 2D layers, whereas the organic amines are inserted between the layers. The formation of 1 demonstrates that solvents play an important role during the synthesis. |
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| Keywords: | Lanthanum Solvothermal synthesis Sulfate Crystal structure |
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