Crystal and molecular structures of the potassium salt of 2-methoxy-4-dimethylamino-6-dinitromethyl-1,3,5-triazine |
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| Authors: | V V Bakharev A A Gidaspov D B Krivolapov E V Mironova I A Litvinov |
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| Institution: | (1) Samara State Technical University, Samara;(2) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan |
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| Abstract: | The X-ray diffraction study of the potassium salt of 2-methoxy-4-dimethylamino-6-dinitromethyl-1,3,5-triazine is carried out. The crystals are triclinic; C7H9N6O 5 ? ·2K+·2H2O; a = 7.645(7) Å, b = 8.230(7) Å, c = 12.435(9) Å; α = 99.99(8)°, β = 91.52(7)°, γ = 113.86(8)°; V = 701(1) Å3, ρcalc = 1.58 g/cm3, Z = 2, space group P-1. The compound crystallizes as a crystalline hydrate with two water molecules. Two planar fragments of dinitromethyl and 2-methoxy-4-dimethylamino-1,3,5-triazine construct the anion. Their geometrical parameters are explored. The coordination of potassium cations and numerous hydrogen bonds are found which result in the development of a complex 3-D framework. |
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| Keywords: | organic chemistry crystal structure salt of 2-methoxy-4-dimethylamino-6-dinitromethyl-1 3 5-triazine |
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