Etudes electrique et Raman de borotungstates et de boromolybdates de lithium vitreux |
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Authors: | Alain Levasseur Mohamed Kbala Mariano Sanz Michel Couzi |
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Affiliation: | 1. Laboratoire de Chimie du Solide du C.N.R.S., 33405 Talence Cedex, France;1. Laboratoire de Chimie Minérale, 33405 Talence Cedex, France;2. Laboratoire de Spectroscopie Infrarouge (associé au CNRS), 33405 Talence Cedex France |
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Abstract: | Conductivity studies of glasses obtained from the B2O3Li2OLi2MoO4 and B2O3Li2OLi2WO4 systems have been carried out. The presence of the transition element in tetrahedral coordination and with two different oxidation states is discussed. A Raman spectroscopy study shows that the MoO4 or WO4 tetrahedra are slightly compressed by the network forming lattice. |
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