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Etudes electrique et Raman de borotungstates et de boromolybdates de lithium vitreux
Authors:Alain Levasseur  Mohamed Kbala  Mariano Sanz  Michel Couzi
Affiliation:1. Laboratoire de Chimie du Solide du C.N.R.S., 33405 Talence Cedex, France;1. Laboratoire de Chimie Minérale, 33405 Talence Cedex, France;2. Laboratoire de Spectroscopie Infrarouge (associé au CNRS), 33405 Talence Cedex France
Abstract:Conductivity studies of glasses obtained from the B2O3Li2OLi2MoO4 and B2O3Li2OLi2WO4 systems have been carried out. The presence of the transition element in tetrahedral coordination and with two different oxidation states is discussed. A Raman spectroscopy study shows that the MoO4 or WO4 tetrahedra are slightly compressed by the network forming lattice.
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