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Chemical approaches for mimicking logic functions within fluorescent MPT dyes
Authors:ChunHu Xu  Wei Sun  Chao Zhang  YanChun Bai  ChenJie Fang  WenTao Li  YanYi Huang  ChunHua Yan
Affiliation:(1) Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, PKU-HKU Joint Laboratory in Rare Earth Materials and Bioinorganic Chemistry, Peking University, Beijing, 100871, China;(2) Department of Advance Materials and Nanotechnology, College of Engineering, Peking University, Beijing, 100871, China
Abstract:The progress of the design, synthesis, fluorescence properties and application of a new family of fluorescent molecular switches towards information processing at the molecular level was reviewed. On the basis of the high fluorescence quantum yields and surroundings-sensitive fluorescent properties of the 5-methoxy-2-(2-pyridyl)-thiazole (2-MPT, 1) and a series of its derivatives as prepared, multiple binary logic and arithmetic functionalities were realized through encoding the controllable fluorescence switching properties with binary digit. Combined with the microfluidic platform, the fabrication of the molecular logic devices was attempted. Supported by the National Natural Science Foundation of China (Grant Nos. 20821091, 20705003 & 20733001) and Peking University Financial Support
Keywords:5-methoxy-2-(2-pyridyl)-thiazole (2-MPT)  surroundings-sensitive fluorescence properties  logic and arithmetic functionalities
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