Photochromism of a radical diffusion-inhibited hexaarylbiimidazole derivative with intense coloration and fast decoloration performance |
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Authors: | Fujita Kana Hatano Sayaka Kato Daisuke Abe Jiro |
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Institution: | Department of Chemistry, School of Science and Engineering, Aoyama Gakuin University, Sagamihara, Kanagawa, Japan. |
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Abstract: | We report the synthesis and the photochromic behavior of a newly designed, photochromic, radical diffusion-inhibited hexaarylbiimidazole (HABI) derivative with markedly improved photochromic performance in coloration and decoloration rates as well as greater optical density in the colored state. The thermal bleaching rate (tau1/2 = 260 ms at 295 K) is the fastest among the reported ones for HABI derivatives. |
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