| 微环电极上线性扫描伏安法准稳态可逆波理论 |
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| 引用本文： | 金葆康,张祖训.微环电极上线性扫描伏安法准稳态可逆波理论[J].化学学报,1994,52(2):181-185. |
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| 作者姓名： | 金葆康 张祖训 |
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| 作者单位： | 南京大学化学系 |
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| 基金项目： | 高等学校博士学科点专项科研基金资助项目 |
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| 摘 要： | 本文求得了适用于不同γ(式(6))和P(式(9))的最大电流表达式,并提出了准稳态的定量标准,还推导了微环电极上线性扫描伏安法准稳态可逆波方程式,经验证,理论和实验结果相符合
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| 关 键 词： | 伏安法 电化学反应 亚稳态 微电极 |
The theory of linear sweep voltammetry for the quasi-steady-state reversible wave at ultramicroring electrode |
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| JIN BAOKANG,ZHANG ZUXUN.The theory of linear sweep voltammetry for the quasi-steady-state reversible wave at ultramicroring electrode[J].Acta Chimica Sinica,1994,52(2):181-185. |
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| Authors: | JIN BAOKANG ZHANG ZUXUN |
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| Abstract: | The expression of the max. current variation with g and P at ultramicroring electrode for linear sweep voltammetry is presented, the rule of judgement for the quasi-steady-state reversible wave is described, and the equation of linear sweep voltammetry for the quasi-steady-state reversible wave is derived also. Experimental results are in good agreement with the theor.6 |
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| Keywords: | VOLTAMMETRY ELECTROCHEMICAL REACTION METASTABLE STATES MICROELECTRODE |
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