A New One-dimensional Zigzag Chain [Zn(1,5-NDC)(2,2′-bipy)]_n Obtained from Hydrothermal Reaction |
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引用本文: | MENG Ze-Rong HE Xiang WU Xiao-Yuan CHEN Li-Juan YANG Wen-Bin LU Can-Zhong②.A New One-dimensional Zigzag Chain [Zn(1,5-NDC)(2,2′-bipy)]_n Obtained from Hydrothermal Reaction[J].结构化学,2006(11). |
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作者姓名: | MENG Ze-Rong HE Xiang WU Xiao-Yuan CHEN Li-Juan YANG Wen-Bin LU Can-Zhong② |
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作者单位: | State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Sciences,Fuzhou,Fujian 350002,China |
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基金项目: | This work was supported by the 973 Program of MOST (001CB108906), NNSFC (90206040, 20425313, 20333070 and 20303021), NSF of Fujian Province (2005HZ01-1) and the Chinese Academy of Sciences |
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摘 要: | 1 INTRODUCTION The coordination polymers have attracted much attention in recent years owning to their fascinating molecular structures and potential applications as catalysts, luminescent materials and magnetic materials1~6]. Consequently, numerous new com- pounds have been produced mostly by using appro- priate organic ligands, especially bridging ligands containing multi-dentate oxygen, nitrogen, or sulfur donors to coordinate with the transition metal centers7~10]. Among them, 1,4…
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A New One-dimensional Zigzag Chain [Zn(1,5-NDC)(2,2′-bipy)]_n Obtained from Hydrothermal Reaction |
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Abstract: | The title compound, Zn(NDC)(2,2′-bipy)]n (NDC = 1,5-naphthalenedicarboxylate, 2,2′- bipy = 2,2′-bipyridine), has been synthesized by a hydrothermal reaction and characterized by single-crystal X-ray diffraction analysis. It crystallizes in monoclinic, space group C2/c with a = 19.967(4), b = 17.158(3), c = 14.276(3) ', β = 129.623(5)°, V = 3767.4(12) '3, Z = 8, C22H14N2O4Zn, Mr = 435.72, Dc = 1.536 g/cm3, F(000) = 1776, μ(MoKa) = 1.336 mm-1, the final R = 0.0777 and wR = 0.2447 for 2032 observed reflections (I > 2σ(I)). The Zn(II) ion is six-coordinated by two nitrogen and four oxygen atoms in a distorted octahedral environment. NDC ligand has a bis(bridging bidentate) coordination mode in the compound. The zinc atoms are linked by carboxylate groups of NDC ligand in bridging mode into a one-dimensional zigzag chain. |
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Keywords: | 1 5-NDC zinc coordination polymer crystal structure |
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