Luminescence of orthovanadates M 3 + M3+(VO4)2 and M 2 + M4+ (VO4)2

The absorption, excitation, and luminescence spectra of vanadates of type M ₃ ⁺ M³⁺(VO₄)₂ and M ₂ ⁺ M⁴⁺(VO₄)₂ are studied, where M⁺ is Na, K, Rb, Cs; M³⁺ is Al, Sc; M⁴⁺ is Zr, Sn, Ti. The luminescence spectra maxima are located at 490–510 nm, while those of the excitation spectra are at 360–375 nm. Temperature characteristics of luminescence and thermostimulated luminescence are studied. The question of activation of complex vanadates by rare-earth ions is considered.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 3, pp. 24–28, March, 1976.